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Beilstein J. Org. Chem. 2015, 11, 2631–2640, doi:10.3762/bjoc.11.282
Graphical Abstract
Scheme 1: Double reductive amination on aldehyde 2 allowed the synthesis of trihydroxypiperidines, among whic...
Scheme 2: Synthesis of key azide intermediate 4 through the double reductive amination strategy from “masked”...
Scheme 3: Tetravalent and nonavalent alkyne scaffolds.
Scheme 4: Synthesis of the tetravalent adduct 7 by CuAAC reaction and its deprotection/purification process t...
Scheme 5: Synthesis of nonavalent adduct 11 by CuAAC reaction and its deprotection.
Scheme 6: Synthesis of the monovalent iminosugar 15 by CuAAC reaction and subsequent deprotection of the hydr...